Silanes & Silicones for Coatings & Paints

		Silanes as adhesion promoters		Silanes as dispersion aids for fillers and pigments
		How to use a silane adhesion promoter?		Polyester modified silicone leveling agent
		Suggested adhesion promoters		Reactive silicones
		Silanes as crosslinkers		Substrate wetting agent
		Silanes as curing agents (hardeners)		Defoamer
		Silanes Selection Decision Tree		Anti-graffiti and easy-clean additives

Silanes as dispersion aids for fillers and pigments

	When the organic group of a silane is not a reactive moiety but an alkyl chain the silane functions as a surface modifier. The hydrophilic surface of most mineral fillers and pigments can be made hydrophobic to be more compatible with hydrophobic organic resins. The hydrophobation that occurs when the alkylsilane binds to the filler particle’s surface allows for improved dispersion into the resin.
	Much more effect Silica, alumina, glass, quartz, porcelain clay Much effect Mica, talc, clay, water and alumina, grammiteiron dust, potassium titanic acid Ratherish effect Asbestos, ferric oxide, zinc oxide, carborundum, silicon nitride Not very effect calcium carbonate, carbon, barium sulphate,boron
	There are three general methods for treating the surfaces of inorganic filler materials before they are added to the organic resins. Wet Method   By mixing a slurry of the inorganic materials in a dilute solution of the silane coupling agent, a highly uniform and precise surface treatment of the inorganic material can be obtained. Dry Method   A high shear, high speed, mixer is used to disperse the silane coupling agent into the inorganic materials. The silane is generally applied either neat or as a concentrated solution. When compared to the Wet Method, the Dry Method is most often preferred for large-scale production, treating a large amount of filler in a relatively short time and generating relatively little mixed waste; however, it is more difficult to obtain uniform treatment with this method. Spray Method   Spray the silane coupling agent on high temperature filler that was just taken out from furnace. The method may omit dry procedure and make the process simplify, but pay attention to perflation and ignite.

	1) CALCULATING THE QUANTITY OF SILANE REQUIRED: The silicone molecule is preferably attached to the surface of the inorganic material as a primer to form a mono-layer. Applying a silane as a primer will produce optimum coupling results between the substrate and the resin to be applied. When used as a primer the required amount of silane can be calculated by the following:
	The actual values may deviate from the calculated value depending on the surface condition of the filler or the silane treating process. The following values may be used as guidelines when the value is unknown. A dilution of 1% silane to filler may be considered as standard. Generally 0.3% to 0.5% is recommended.
	Surface area of filler (m2/g) E-glass 0.1 - 0.12 Quartz 1 - 2 Kolin 7 Clay 7 Talc 7 Aluminum polysilicate 1 Calcium carbonate 5 Calcium silicate 2.6
	2) REACTIVITY: The alkoxy groups of the coupling agents react with water to form silanol groups which immediately form covalent bonds by dehydration and condensation:

Product Name	Minimum Coverage Area(m2/g)
SiSiB® PC1110	436
SiSiB® PC1100	353
SiSiB® PC3100	330
SiSiB® PC4100	314
SiSiB® PC2300	398
SiSiB® PC1220	380
SiSiB® PC1200	351